The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.
A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC / Airi, A.; Atzori, C.; Bonino, F.; Damin, A.; Oien-ODegaard, S.; Aunan, E.; Bordiga, S.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 49:1(2019), pp. 12-16. [10.1039/c9dt04112e]
A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC
Airi A.;
2019
Abstract
The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.File in questo prodotto:
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