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EnglishThe second harmonic generation (SHG) properties of two MOFs, obtained from fructose and calcium chloride, were studied using a Non-Linear Optics Multimodal microscope. The first-order hyperpolarizability and the second-order susceptibility were calculated at the DFT level of theory. Moreover, a semi-classical approach to non-linearities in the optical behaviour was used in order to determine the features responsible for the SHG. The MOFs were synthesized both in ethanol and by solid–solid interaction, with a simple, rapid and low-cost methodology with no environmental impact, and were characterized with IR and RAMAN spectroscopy and both the single-crystal and powder X-ray diffraction. Both the metal–carbohydrate-based MOFs show an interesting SHG intensity: in particular, compound 1 shows an average SH intensity more than twice that of sucrose, in agreement with the theoretical results. A favourable combination of optical properties, transparency, thermal and chemical stability makes compound 1 a potential candidate for applications in electro-optics devices.
Non-linear optical properties of β-D-fructopyranose calcium chloride MOFs: an experimental and theoretical approach / Marabello, Domenica; Antoniotti, Paola; Benzi, Paola; Canepa, Carlo; Diana, Eliano; Operti, Lorenza; Mortati, Leonardo; Sassi, Maria Paola. - In: JOURNAL OF MATERIALS SCIENCE. - ISSN 0022-2461. - 50:12(2015), pp. 4330-4341.
| Titolo: | Non-linear optical properties of β-D-fructopyranose calcium chloride MOFs: an experimental and theoretical approach |
| Autori: | |
| Data di pubblicazione: | 2015 |
| Rivista: | |
| Citazione: | Non-linear optical properties of β-D-fructopyranose calcium chloride MOFs: an experimental and theoretical approach / Marabello, Domenica; Antoniotti, Paola; Benzi, Paola; Canepa, Carlo; Diana, Eliano; Operti, Lorenza; Mortati, Leonardo; Sassi, Maria Paola. - In: JOURNAL OF MATERIALS SCIENCE. - ISSN 0022-2461. - 50:12(2015), pp. 4330-4341. |
| Abstract: | The second harmonic generation (SHG) properties of two MOFs, obtained from fructose and calcium chloride, were studied using a Non-Linear Optics Multimodal microscope. The first-order hyperpolarizability and the second-order susceptibility were calculated at the DFT level of theory. Moreover, a semi-classical approach to non-linearities in the optical behaviour was used in order to determine the features responsible for the SHG. The MOFs were synthesized both in ethanol and by solid–solid interaction, with a simple, rapid and low-cost methodology with no environmental impact, and were characterized with IR and RAMAN spectroscopy and both the single-crystal and powder X-ray diffraction. Both the metal–carbohydrate-based MOFs show an interesting SHG intensity: in particular, compound 1 shows an average SH intensity more than twice that of sucrose, in agreement with the theoretical results. A favourable combination of optical properties, transparency, thermal and chemical stability makes compound 1 a potential candidate for applications in electro-optics devices. |
| Handle: | http://hdl.handle.net/11696/52564 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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