This paper purpose is to re-calculate thermodynamic or chemical–physical properties according to thermodynamic temperature T, where measured temperature values were obtained according to the ITS-90, T90 (or the reverse). The main aims of the calculations are: to remove the discontinuity of the first derivative at 273.16 K that is intrinsic in the ITS-90 definition; to use a single cubic spline to model the database of the available experimental data over the whole temperature range (2.37 to 1235) K, while maximising the medium-range smoothness of the correction function; to compute corrections using only local polynomial coefficients.
Thermodynamic temperature differences from the ITS-90 for the correction of thermodynamic property data / Pavese, F.; Ciarlini, P.; Steur, PETRUS PAULUS MARI. - In: JOURNAL OF CHEMICAL THERMODYNAMICS. - ISSN 0021-9614. - 43:(2011), pp. 75-79. [10.1016/j.jct.2010.08.003]
Thermodynamic temperature differences from the ITS-90 for the correction of thermodynamic property data
STEUR, PETRUS PAULUS MARI
2011
Abstract
This paper purpose is to re-calculate thermodynamic or chemical–physical properties according to thermodynamic temperature T, where measured temperature values were obtained according to the ITS-90, T90 (or the reverse). The main aims of the calculations are: to remove the discontinuity of the first derivative at 273.16 K that is intrinsic in the ITS-90 definition; to use a single cubic spline to model the database of the available experimental data over the whole temperature range (2.37 to 1235) K, while maximising the medium-range smoothness of the correction function; to compute corrections using only local polynomial coefficients.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.